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A Facile Total Synthesis of (±)-Acoragermacrone by Titanium-Induced Keto Ester Cyclization

✍ Scribed by Weidong Li; Ying Li; Yulin Li

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
143 KB
Volume
102
Category
Article
ISSN
0037-9646

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✦ Synopsis

Abstract

(±)‐Acoragermacrone, a natural occurring germacrane‐type sesquiterpenoid, was synthesized from geranyl acetate via eight steps by employing titanium‐induced intramolecular keto α,β‐unsaturated ester coupling as key step.

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