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A facile synthesis of β-substituted-α-allenyl primary amines

✍ Scribed by James R McCarthy; Charlotte L Barney; Donald P Matthews; Thomas M Bargar

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
244 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

Copper or nickel catalyzed substitution of Grignard reagents on the bistrimethylsilyl protected 4-methoxy-2-butynylamine (2) provides B-substituted-a-allenyl primary amines (3) in high yield.

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