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A Facile Synthesis of α-Phenylseleno-α,β-unsaturated Nitriles via α-Phenylselenenyl Cyanomethylene Triphenylarsorane.

✍ Scribed by Gui-Sheng Deng; Zhi-Zhen Huang; Xian Huang

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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The reaction of Ph 3 P‫ס‬NLi with various ␣,b-unsaturated esters gives access to new N-(␣,b-unsaturated acyl) phosphinimines, which can undergo intramolecular aza-Wittig reactions