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A facile synthesis of strained bridgehead olefins by a gas-phase elimination reaction

✍ Scribed by Konrad B. Becker; Rudolf W. Pfluger

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
228 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

A synthesis of bicyclo[3.3.llnon-1-ene 1 and of a 1O:l mixture of b?cyclo[4.2.llnon-l(8)-ene 2 and bicyclo[4.2.lln&-l(2)-ene 3 by gas-phase pyrolysis of the correspondTng bridgehead acetates and chlor:des is reported.

A number of different syntheses are available for the preparation of the methylene-bridged trans-cyclooctene bicyclo[3.3.

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