A facile synthesis of 3-phenylthio and 3-methoxy substituted furans from 3-methoxy-1-phenylthio-1-propyne
β Scribed by Hsi-Hwa Tso; Hongru Tsay
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 98 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
A new method for the highly stereoselective synthesis of (Z)-l-phenylthio-l-trialkylsilylalkenes 3 by the elimination of methanol from 1-methoxy-l-phenylthio-l-trialkylsilylalkane 2 in organic solvents is described.
Both 1,3-and 1.4-diketones are obtained from common precursors, A-methoxy-Y-phenylthio ketones. These compounds are derived through the novel phenylthio migration reaction of the aldehyde adducts with methoxy(phenylthio)methane upon exposure to enol silyl ethers. The compounds thus obtained are conv
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