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A facile synthesis of 2-deoxy-2-hydroxymethyl-β-D-erythrofuranosyl nucleosides from 9-(2-deoxy-2-hydroxymethyl-β-D-erythrooxetanosyl)adenine by a novel ring expansion accompanying transglycosidation

✍ Scribed by Kuniki Kato; Takae Minami; Tomohisa Takita; Shigeru Nishiyama; Shosuke Yamamura; Hiroshi Naganawa


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
126 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


Reaction of N-benzoyl oxetanocin diacetate with trimethylsilyl pyrimidine in the presence of SnC14 gives both erythrofuranosyl pyrimidine and purine nucleosides.


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