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A Facile Skeletal Rearrangement. Reidentification of “2,2,4-Trimethylpentane-1,4-diol” 1

✍ Scribed by Wilcox, Charles F.; Nealy, David L.

Book ID
121345756
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
588 KB
Volume
28
Category
Article
ISSN
0022-3263

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Magnetic nonequivalences in 2,2,4-trimet
Magnetic nonequivalences in 2,2,4-trimethylpentane-1,3-diol diisobutyrate and diacetate
✍ Richard M. Fantazier 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 692 KB

## Abstract 2,2,4‐Trimethylpentane‐1,3‐diol diisobutyrate (**1**) and diacetate (**2**) exhibit magnetic nonequivalence for both sets of __geminal__‐dimethyl groups adjacent to the asymmetric center, and nonequivalence of the methylene protons three bonds removed. Solvent and temperature studies in