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A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene

โœ Scribed by Ghadwal, Rajendra S.; Roesky, Herbert W.; Granitzka, Markus; Stalke, Dietmar


Book ID
127050248
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
557 KB
Volume
132
Category
Article
ISSN
0002-7863

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A General Synthetic Route to Mixed NHCโ€“P
โœ Serena Fantasia; Stevenโ€…P. Nolan ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 341 KB ๐Ÿ‘ 2 views

## Abstract Mixed NHCโ€“phosphane palladium(0) complexes [(NHC)Pd(PR~3~)] (NHC: Nโ€heterocyclic carbene) are synthesized directly from commercially available reagents, with the possibility to tune the nature of both the NHC and the phosphane. Reaction of [(NHC)Pd(allyl)Cl] (palladium source) and PR~3~