A facile reduction of Ar3COH to Ar3CH
โ Scribed by Valeryi Shevchenko; Robert Engel
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 156 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
โฆ Synopsis
Modification of the conditions described for the preparation of triarylmethylphosphonous acids from hypophosphorous acid and triarylmethanols allows facile reduction of the C-O-H linkage to the C-H linkage.
๐ SIMILAR VOLUMES
The thermochemical data tif\_ ,," and AS:\_,," for clustering reactions CHf (Ar).\_, +Ar=CHf (Ai),, were determined with a pulsed electron beam high-pressure mass spectrometer. It was found that (1) the bond energy of CH: (Ar), with n= 1 (-AH& = Il.3 kcal/mol) is much higher than that with n=2 ( -AH
## Abstract The reaction between methyl and hydroxyl radicals has been studied in reflected shock wave experiments using narrowโlinewidth OH laser absorption. OH radicals were generated by the rapid thermal decomposition of tertโbutyl hydroperoxide. Two different species were used as CH~3~ radical