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A facile preparation of dialkyl phosphonate compounds from sterically hindered p-nitrocumyl halides through the SRN1 mechanism

✍ Scribed by Jong Uk Rhee; Glen A. Russell; Woonphil Baik

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 236 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01925-x

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✦ Synopsis

p-Nitrobenzyl phosphonate anion with p-nitrocumyl halides gives a good yield of the coupling product dialkyl[(1,1-dimethyl-l,2-di-(p-nitrobenzyl)ethyl] phosphonates through the S~N1 mechanism. The reaction was greatly accelerated by sunlamp irradiation but inhibited by the radical scavenger (t-Bu)2NO'.

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1999 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 06 -149 A Facile Preparation of Dialkyl Phosphonate Compounds from Sterically Hindered p-Nitrocumyl Halides Through the S RN 1 Mechanism. -The reaction of the anion derived from p-ni