A Facile Method for the Synthesis of Hydrazine-4-oxothiazolidine and Imino-5-oxothiadiazine Derivatives from 1,4-Disubstituted Thiosemicarbazides
β Scribed by Hassan, Alaa A.; Aly, Ashraf A.; Bedair, Tarek I. M.; Brown, Alan B.; El-Emary, Talaat I.
- Book ID
- 121748752
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 549 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-152X
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The reaction of 3,6-diaryl-1,2,4,5-tetrazines and 2-aryl substituted acetonitriles, under basic conditions, leads unexpectedly to 3,5-diaryl-(NH)-1,2,4-triazoles in moderate yields. A mechanism is proposed.
## Abstract magnified image Electrochemical oxidation of catechols to corresponding __o__βquinones was successfully performed in aqueous solution by electrolysis at the controlled potentials. Quinones derived from catechols, participate in Michael addition reactions with 5βphenylβ1,3,4βoxadiazoleβ
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