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A facile method for the preparation of 6-epi-penicillins

✍ Scribed by A. Vlietinck; E. Roets; P. Claes; H. Vanderhaeghe

Book ID
108383293
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
184 KB
Volume
13
Category
Article
ISSN
0040-4039

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Fluorinated vinyl iodide% RlCF=CFI [where Rl=F, CFs, Ph, (iPrC)sP(O)], couple directly with 1-alkynes in the presence of palladium and cuprous iodide in triethylamine to give excellent yields of the fluorinated enynes. Recent reports have demonstrated the importance of enynes in organic synthesis.