A Facile Method for Controlling the Molecular Weight of Hyperbranched Light-Emitting Polymers
β Scribed by Qingguo He; Hongmin Huang; Fenglian Bai; Yong Cao
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 122 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1022-1336
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β¦ Synopsis
Abstract
Summary: Two series of hyperbranched conjugated polymers were synthesized via an A~3~β+βB~2~ type Wittig reaction. The molecular weights of the polymers were successfully tuned by simply changing the feed ratio of the monomers. Polymers with higher molecular weights presented more efficient photoluminescence, higher thermal stability and higher performance of LEDs.
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π SIMILAR VOLUMES
A rapid method for determining the molecular weight distribution of polymers has been the aim of polymer chemists for a long time. The method presented here requires less tban two hours, including dissolution of the polymer. It is an exteneion of a photoelectric turbidimetric technique presented by