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A facile, high-yield synthesis of trans-Fe(CO)3(PR3)2 from Fe(CO)5, Fe(CO)4CHO-, HFe(CO)4-, or HFe(CO)3PR3-

✍ Scribed by Keiter, Richard L.; Keiter, Ellen A.; Hecker, Karl H.; Boecker, Carol A.


Book ID
121307040
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
572 KB
Volume
7
Category
Article
ISSN
0276-7333

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Heterometallic Nitrido-Carbonyl Clusters
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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit