✦ LIBER ✦

A facile generation of radical cations via the action of nitroxides

✍ Scribed by Liu You-Cheng; Liu Zhong-Li; Wu Lung-Min; Chen Ping

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 139 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98991-3

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✦ Synopsis

Radical cations of aromaticamines and heteroaromatics were generated via the action of nitroxides in methylene chloride in the presence of trifluoroacetic acid. Interest in radical cations has dramatically expanded since last decade. Chemical methods which have been used to generate radical cations involve oxidation in concentrated sulfuric acid, oxidation by Lewis acids, by halogens and by metal ions etc.

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