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A Facile Conversion of Tertiary Alcohols to Olefins

✍ Scribed by Yadav, J S; Mysorekar, Sudha V

Book ID: 120268908
Publisher: Taylor and Francis Group
Year: 1989
Tongue: English
Weight: 163 KB
Volume: 19
Category: Article
ISSN: 0039-7911
DOI: 10.1080/00397918908051028

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We wish to report that treatment of dimethanesulfonates (dimesylates) of vie diols with sodium anthracene or naphthalene in THF or dimethoxyethane (ME) affords a rapid and high yield conversion to the corresponding alkene. Generally. the best technique is to slowly add an approximately 0.3 E solutio