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A facile conversion of a 310 helical structure to a cyclic β-turn mimic in dehydrophenylalanine-derived small peptides through ring-closing metathesis

✍ Scribed by T.V.R.S Sastry; Biswadip Banerji; S Kiran Kumar; A.C Kunwar; Jagattaran Das; Jyoti Prokash Nandy; Javed Iqbal

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 188 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01601-5

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✦ Synopsis

Dehydrophenylalanine-derived small peptides can be preorganized in a 3 10 helical structure which is transformed into a b-turn mimic during a ring-closing metathesis cyclization.

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