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A facile and efficient stereoselective synthesis of 6-hydroxy-trans-4a-phenyldecahydroisoquinoline

โœ Scribed by Shinzo Kano; Tsutomu Yokomatsu; Yoko Yuasa; Shiroshi Shibuya

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
144 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A stereoselective synthesis of 6-oxygenated trans-4a-phenyldecahydroisoquinoline was achieved by treatment of l-ethoxycarbamoyl-l-phenyl-l,S-hexadiene with paraformaldehyde in formic acid.

We investigated a stereoselective synthesis of 6-oxygenated trans-4a-phenyldecahydroisoquinoline system, a key structural variant of morphine moleculel.

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