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A facile and efficient asymmetric synthesis of (+)-salsolidine

✍ Scribed by Daisuke Taniyama; Masayoshi Hasegawa; Kiyoshi Tomioka


Book ID
104210509
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
222 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


A three-key step methodology involving a highly selective asymmetric addition of an organolithium reagent to an N-naphthalenylimine, cyclization and oxidative removal of the N-naphthalenyl group provided a facile and ecient synthetic way to (+)-salsolidine.


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A facile and efficient synthesis of bisa
✍ Abdel-Zaher Abdel-Aziz Elassar πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 110 KB πŸ‘ 1 views

## Abstract 1,4‐Phenylenediamine was condensed with acetylacetone to give 4,4′‐[1,4‐phenylenedi‐(nitrilo)]‐dipenten‐2‐ol **1**. Compound **1** reacted with different organic reagent to give bisazine derivatives. Β© 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:293–299, 2004; Published online in Wi