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A facile 1,5-rearrangement of β-formylenamides and cleavage of esters catalysed by Pseudomonas fluorescens

✍ Scribed by U Bora; M Longchar; A Chetia; B.S.D Kumar; R.C Boruah; J.S Sandhu

Book ID: 104250540
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 309 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00114-4

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✦ Synopsis

Formylenamides undergo a facile 1,5-rearrangement of their N-acetyl groups under the influence of the soil bacterium Pseudomonas fluorescens to afford b-acetoxyenones in good yields. Further, the soil microorganism efficiently cleaves steroidal and non-steroidal acetates to alcohols.

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