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A (.eta.1-iminoacyl)zirconocene complex formed by alkyl isocyanide insertion into the metal-to-carbon bond of (.eta.2-formaldehyde)zirconocene

✍ Scribed by Erker, Gerhard.; Mena, Miguel.; Krueger, Carl.; Noe, Ralf.

Book ID: 126979395
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 407 KB
Volume: 10
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00050a064

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📜 SIMILAR VOLUMES

Formation of .eta.1-iminoacyl compounds

Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)

✍ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 916 KB