𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A dynamical model for liquid water

✍ Scribed by G. Wilse Robinson; J. Lee; K.G. Casey; D. Statman

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
576 KB
Volume
123
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Anomalies in liquid water are attributed to librattona~/rotattonal mottons, which depend cooperatively on H-bond structure within relatively stable oxygen groupings.

The close relationships between small-ion hydratton dynamics, spin-lattice and dielectric relaxation ttmes, and shear viscostty are delineated. Within this context, the anomalous heat capacity of Oguni and Angel1 can be understood. * Figs. 7 and 8 of ref. [lS] indicate a 150-160 cm-l llbrational shift between 275 and 365 K.

📜 SIMILAR VOLUMES

A “microscopic” model for the dynamics o
A “microscopic” model for the dynamics of water
✍ Davide Bertolini; Mario Cassettari; Mauro Ferrario; Giuseppe Salvetti; Paolo Gri 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 562 KB

A "reduced" model for the dipolar relJ\ation of x\dter taking hydrogen-bond dynamics into account is built up. Via proper diffusional assumptions this leads us to study dielectric relaxation in terms of some relevant statistical properties of the hydrogen bond. The resulting relationship is shown to