We report the study of translational-vibrational energy transfer in the A + BC scattering using the dynamical Lie algebraic approach combined with the intermediate picture. The rotational sudden approximation is applied to treat the rotational motion of the BC molecule, which is regarded as an anhar
A dynamical Lie algebraic mehtod for quantum reactive scattering
β Scribed by Daren Guan; Xizhang Yi; Shiliang Ding; Benhui Yang; Dongming Hua
- Publisher
- SP Science China Press
- Year
- 1998
- Tongue
- English
- Weight
- 549 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1674-7291
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π SIMILAR VOLUMES
The dynamical Lie algebraic approach developed by Y. Alhassid and R. D. Levine (Phys Rev A 1978, 18, 89) combined with the intermediate picture is applied to the study of translational-vibrational energy transfer in the collinear collision between an atom and an anharmonic oscillator. By solving equ
## Abstract The adoption of evenly spaced grids in the soβcalled bond order coordinates for the calculation of diatomic eigenfunctions in reactive scattering problems is investigated. These grids (used here for the first time in reactive dynamics) sample the accessible space better than traditional