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A Double Iodoetherification of σ-Symmetric Diene Acetals for Installing Four Stereogenic Centers in a Single Operation: Short Asymmetric Total Synthesis of Rubrenolide

✍ Scribed by Hiromichi Fujioka; Yusuke Ohba; Hideki Hirose; Kenichi Murai; Yasuyuki Kita

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
128 KB
Volume
44
Category
Article
ISSN
0044-8249

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A Double Iodoetherification of σ-Symmetr
A Double Iodoetherification of σ-Symmetric Diene Acetals for Installing Four Stereogenic Centers in a Single Operation: Short Asymmetric Total Synthesis of Rubrenolide
✍ Hiromichi Fujioka; Yusuke Ohba; Hideki Hirose; Kenichi Murai; Yasuyuki Kita 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

Many biologically active natural products contain multiple chiral centers and occur in their optically active form, and therefore the development of methodologies that can lead to multiple chiral centers is desirable in synthetic organic chemistry. Recently, we developed the intramolecular haloether