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A DNMR study of syn/anti-isomerization in Z,Z-9,10-bis(styryl)anthracene

✍ Scribed by Mikael Sundahl; Olof Wennerström


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
263 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


A&l-act. Two isomers of Z,Z-9,10-bis(styryl)anthracene have been observed by 1H and 1% NMR spectroscopy. The t3C chemical shifts were assigned by the 1%tH HETCOR technique. The barrier to interconversion of these two isomers is measured to 18 kcal/mol. The syvn isomer forms a charge transfer complex with trinitrobenzene (TNB) as determined by 1 H NMR methods