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A Diversity Oriented Synthesis of Highly Functionalized Unsymmetrical Biaryls Through Carbanion Induced Ring Transformation of 2H-Pyran-2-ones.

✍ Scribed by Nidhi Agarwal; Abhishek S. Saxena; Farhanullah Farhanullah; Atul Goel; Vishnu J. Ram


Publisher
John Wiley and Sons
Year
2003
Weight
155 KB
Volume
34
Category
Article
ISSN
0931-7597

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Pyrazolo[1,5-a]pyridines (3) and pyrano [4,3-d]pyrazolo [1,5-achieved from the reaction of 2 with polarised ketene dithioacetals (5) and arylidenemalononitrile, respectively. An a]pyridines (4) have been synthesized from the reaction of pyran-2-one (1) and 5-aryl-3-cyanomethyl-1H-pyrazole (2) analog