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A Diversity-Oriented Approach to Diphenylalkanes by Strategic Utilization of [2+2+2] Cyclotrimerization, Cross-Enyne Metathesis and Diels–Alder Reaction

✍ Scribed by Sambasivarao Kotha; Priti Khedkar

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
213 KB
Volume
2009
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

A novel and efficient approach towards the synthesis of polysubstituted diphenylalkane derivatives have been demonstrated using a strategic combination of [2+2+2] cyclotrimerization, ethylene cross‐enyne metathesis and Diels–Alder reaction as key steps. The strategy involves the stepwise functionalization of acetylenic termini of α,ω‐diyne scaffold to build functionalized aromatic units.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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