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A Diruthenum(III) Complex Possessing a Diazine and Two Chloride Bridges: Synthesis, Structure, and Properties

✍ Scribed by Pal, Satyanarayan; Pal, Samudranil


Book ID
126218875
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
57 KB
Volume
40
Category
Article
ISSN
0020-1669

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The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice