A direct synthetic approach to functionalized divinylcyclopropanes and cycloheptadienes.
✍ Scribed by J.P. Marino; L.J. Browne
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 145 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
We have recently described a novel and general synthetic approach to ring-fused cycloheptadienes & functionalized divinylcyclopropenes. 1 In this approach, the divinylcyclopropane system was constructed by a two-step sequence involving a carbonyl-stabilized vinylsulfoxonium methylide and a Wittig reaction. The methodology utilized the combination of two three-car-
📜 SIMILAR VOLUMES
## Abstract The activation parameters of the thermal rearrangements of the __trans__‐divinylcyclopropanes **1** and **2**, and of __cis__‐divinylcyclopropane **3** to give cycloheptadiene **5** have been determined. In addition it has been shown that __trans__‐divinylcyclopropane‐cycloheptadiene re
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