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A Direct Synthesis of 1,3,5-Tri-t-butylbenzene

โœ Scribed by Myhre, P. C.; Rieger, Terrill; Stone, J. T.


Book ID
121462365
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
300 KB
Volume
31
Category
Article
ISSN
0022-3263

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1,2,4,5-Tetra-l-butylbenzene (394) (TTBB) is believed to be a highly strained boat-shaped molecule (4) (I) and so might be expected to undergo photoisomerisation to a Dewar benzene (II) more readily than does 1,2,4-trit-butylbenzene(5'6), which was the first compound reported to undergo such a conve