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A Diosphenol-Based Strategy for the Total Synthesis of (−)-Terpestacin

✍ Scribed by Trost, Barry M.; Dong, Guangbin; Vance, Jennifer A.

Book ID
115314146
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
62 KB
Volume
129
Category
Article
ISSN
0002-7863

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Cyclic 1,2-Diketones as Core Building Blocks: A Strategy for the Total Synthesis of (−)-Terpestacin
✍ Barry M. Trost; Guangbin Dong; Jennifer A. Vance 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 503 KB

## Abstract We report a full account of our work towards the total synthesis of (−)‐terpestacin (**1**), a sesterterpene originally isolated from fungal strain __Arthrinium__ sp. FA1744. Its promising anti‐HIV and anti‐cancer activity, as well as its novel structure, make terpestacin an attractive