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A dinuclear cyano-bridged complex based on hexacyanoferrate(III) and samarium(III) nitrate: synthesis and crystal structure

โœ Scribed by Hui-Zhong Kou; Guang-Ming Yang; Dai-Zheng Liao; Peng Cheng; Zong-Hui Jiang; Shi-Ping Yan; Xiao-Ying Huang; Geng-Lin Wang


Book ID
110411989
Publisher
Springer
Year
1998
Tongue
English
Weight
435 KB
Volume
28
Category
Article
ISSN
1572-8854

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โœ John Springborg; Margareta Zehnder ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 449 KB

The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice