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A Diene—Retrodiene—Diene Reaction. The Synthesis of 2,3,5,6-Tetrakis(trifluoromethyl)-7-oxabicyclo[2.2.1]-2,5-heptadiene

✍ Scribed by Weis, C. D.


Book ID
121422232
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
361 KB
Volume
27
Category
Article
ISSN
0022-3263

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## Abstract The photochemistry of 1,3,3‐trimethylbicyclo[2.2.2]octa‐5,7‐dien‐2‐ones **1a**–**f** containing multiple chromophoric moieties under various conditions is described. Upon direct irradiation, dienones **1a**–**f** in benzene, acetonitrile, and methanol were found to aromatize through pho