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A diels-alder-type adduct from Artocarpus heterophyllus

โœ Scribed by Kazuki Shinomiya; Miwa Aida; Yoshio Hano; Taro Nomura


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
166 KB
Volume
40
Category
Article
ISSN
0031-9422

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Syntheses of deoxyhexoses from diastereo
โœ Tomasz Bauer ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 269 KB

Syntheses of deoxyhexoses are presented. The concept is based on the functionalization of enantiomerically pure 6-hydroxymethyl-2-methoxy-5,6-dihydro-2H-pyran, which is easily synthesized by asymmetric hetero-Diels-Alder reaction. Methyl 4,6-dideoxy-a-o-arabino-hexopyranoside, methyl a-o-chalcoside