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A (Diborole)cobalt Complex with a C–H···B Bridge, CpCo(1,3-C3B2Me5H), and Its Thallium Derivative: Synthesis, Structure, and Bonding

✍ Scribed by Dmitry V. Muratov; Alexander S. Romanov; Pavel V. Petrovskii; Mikhail Yu. Antipin; Walter Siebert; Alexander R. Kudinov

Book ID
112082444
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
734 KB
Volume
2012
Category
Article
ISSN
1434-1948

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Complexes of the (Tetramethylcyclobutadiene)cobalt Fragment with Boratabenzene Ligands and an Unprecedented Formation of a Borabenzene Complex − Structures of (C4Me4)Co(3,5-Me2C5H3BSnMe3) with an Sn−B Bond and of the Dinuclear Complex [(C4Me4)Co(3,5-Me2C5H3B)]2O
✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th