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A diborane(6) bridged diiron hexacarbonyl: preparation of B2H6Fe2(CO)6

โœ Scribed by Andersen, Earl L.; Fehlner, Thomas P.


Book ID
120358150
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
319 KB
Volume
100
Category
Article
ISSN
0002-7863

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โœ W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 253 KB ๐Ÿ‘ 1 views

The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3ยฑn (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri