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A DFT/TDDFT study of the excited state intramolecular proton transfer based sensing mechanism for the aqueous fluoride chemosensor BTTPB

✍ Scribed by Chen, Jun-Sheng ;Zhou, Pan-Wang ;Zhao, Li ;Chu, Tian-Shu


Book ID
121404606
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
733 KB
Volume
4
Category
Article
ISSN
2046-2069

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✍ Guang-Yue Li; Guang-Jiu Zhao; Yu-Hui Liu; Ke-Li Han; Guo-Zhong He 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 555 KB

## Abstract An excited‐state proton transfer (ESPT) process, induced by both intermolecular and intramolecular hydrogen‐bonding interactions, is proposed to account for the fluorescence sensing mechanism of a fluoride chemosensor, phenyl‐1__H__‐anthra(1,2‐__d__)imidazole‐6,11‐dione. The time‐depend