A DFT study on the hydrated V2O5-TiO2-anatase catalyst: stability of monomeric species
✍ Scribed by Mònica Calatayud; Basma Mguig; Christian Minot
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 487 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1432-2234
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The catalyst V 2 O 5 /TiO 2 (anatase) is an important industrial catalyst for the partial oxidation of hydrocarbons. Its catalytic properties are probably related to a specific interface and surface overlayer structure. Model catalysts of V 2 O 5 /TiO 2 were prepared by depositing thin V 2 O 5 layer
¨Dedicated to Prof. H. Knozinger on the occasion of his 65th birthday. Äbstract Supported model catalysts exclusively exposing monomeric vanadyl species were prepared by washing V O rTiO 2 5 2 Ž . samples Eurocat EL10V1 and EL10V8 with aqueous solutions of ammonia. FT-NIR Raman spectroscopy confirm