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A DFT Study of the Mechanism of the Spontaneous Activation of H2 by Ni, Pd, Pt, and Pd2.

✍ Scribed by M. E. Alikhani; C. Minot


Publisher
John Wiley and Sons
Year
2003
Weight
50 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract **An even split**: In sharp contrast with the general behavior of Pd^0^ complexes, [Pd(IPr)(PCy~3~)] is able to activate the Hο£ΏH bond. The resulting __trans__‐[Pd(H)~2~(IPr)(PCy~3~)] is the first isolated mononuclear dihydride palladium compound. Its formation is supported by multinucle