A detailed kinetic study of the RAFT polymerization of a bi-substituted acrylamide derivative: influence of experimental parameters
✍ Scribed by Arnaud Favier; Marie-Thérèse Charreyre; Christian Pichot
- Book ID
- 108247907
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 832 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0032-3861
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## Abstract **Summary:** A kinetic analysis of living/controlled radical polymerizations in bulk mediated by RAFT is presented. The main objective is to show how the kinetics of the RAFT process and, in particular, of the RAFT intermediate radical is affecting the overall polymerization rate. Namel
Acrylamide was polymerized in acetonitrile at 82 °C with a perfluorinated azo-derivative initiator. The polymerization proceeded heterogeneously. Varying amounts of initiator and monomer were used. The activation energy was deduced from three experiments carried out at 59, 71, and 82 °C. The followi