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A Density Functional Theory Study of the Mechanism of Free Radical Generation in the System Vanadate/PCA/H 2 O 2

✍ Scribed by Khaliullin, Rustam Z.; Bell, Alexis T.; Head-Gordon, Martin


Book ID
121353341
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
278 KB
Volume
109
Category
Article
ISSN
0022-3654

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## Abstract Formation of free radical intermediates in a NaOH/H~2~O~2~/Fe(III) system has been studied by ESR spectroscopy in the presence of the spin trap 5,5‐dimethy‐1‐pyrroline __N__‐oxide (DMPO). DMPO/O^βˆ’^ and DMPO/^β€’^OH signals were simultaneously detected in this system, but only the DMPO/^β€’^