A deformational mechanism in particulate-filled glassy polymers
โ Scribed by R. E. Lavengood; L. Nicolais; M. Narkis
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 767 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
The stress-strain behavior of glass bead-filled polystyrene, styrene-acrylonitrile, styrene-acrylonitrile-butadiene, and polyphenglene oxide composites is studied at various temperatures below their glass transition temperature. Earlier studies of beadfilled composites indicated that the addition of filler decreases toughness and ultimate elongation. Our results show that while this is true for certain conditions, it is also possible for such composites to have higher toughness and ultimate elongation than the unfilled matrices. A deformational mechanism, involving crazing of the matrix, is proposed which explains this behavior.
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On the basis of known nonlinearity of intermolecular force fields, we discuss the interpretation of PVT (pressure, volume, and temperature) behavior, pressure-temperature superposition for polymers, and the relationship between yield stress and tensile modulus. For PVT behavior of polymers, our theo
Hai f a, Isra e 1 ## Synopsis A semiempirical, single-parameter equation describes the modulus of particulate systems This equation has been found applicable for thermoplastic/glass bead systems, and it is further verified for particulate thermosetting systems (epoxy and polyester matrices). The