A crystal structure of mixed-metal dianionic phosphate Cs3.70Mg0.60Ti2.78(TiO)3(P2O7)4(PO4)2

✍ Scribed by Ivan V. Ogorodnyk; Igor V. Zatovsky; Nikolay S. Slobodyanik; Vyacheslav N. Baumer; Oleg V. Shishkin

• Publisher: Elsevier Science
• Year: 2006
• Tongue: English
• Weight: 401 KB
• Volume: 179
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1016/j.jssc.2006.08.013

✦ Synopsis

The single crystals of caesium magnesium titanium (IV) tri-oxo-tetrakis-diphosphate bis-monophosphate, Cs 3.70 Mg 0.60 Ti 2.78 (TiO) 3 (P 2 O 7 ) 4 (PO 4 ) 2 , crystallize in sp. gr. P-1 (No. 2) with cell parameters a ¼ 6.3245( 4), b ¼ 9.5470(4), c ¼ 15.1892(9) A ˚, a ¼ 72.760(4), b ¼ 85.689(5), g ¼ 73.717(4), z ¼ 1. The titled compound possesses a three-dimensional tunnel structure built by the corner-sharing of distorted [TiO 6 ] octahedra, [Ti 2 O 11 ] bioctahedra, [PO 4 ] monophosphate and [P 2 O 7 ] pyrophosphate groups. The Cs + cations are located in the tunnels. The partial substitution of Ti positions with Mg atoms is observed. The negative charge of the framework is balanced by Cs cations and Mg atoms leading to pronounced concurrency and orientation disorder in the [P 2 O 7 ] groups, which coordinate both.