## Abstract Critical evaluations of the microwave effect on initiation, propagation, and termination during conventional radical polymerizations (RPs) of methyl methacrylate (MMA) and random copolymerization of styrene (St) with (meth)acrylates are examined by comparing microwave heating (MWH) and
A Critical Investigation on the Occurrence of Microwave Effects in Emulsion Polymerizations
β Scribed by Hayden, Stephan; Studentschnig, Alexander F. H.; Schober, Sigurd; Kappe, C. Oliver
- Book ID
- 126522180
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 547 KB
- Volume
- 215
- Category
- Article
- ISSN
- 1022-1352
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Styrene ab initio emulsion polymerizations were conducted at 70ΠC in an automated reaction calorimeter. Two polymerizations were performed, one above and the other below the critical micelle concentration (CMC) of the surfactant, thus ensuring differing polymerization kinetics between the two: the s
## Abstract Rate constants of the ringβopening polymerization (ROP) of __Ξ΅__βcaprolactone (__Ξ΅__βCL) by microwave heating (MH) and flash conventional heating (FCH) have been measured. The reaction is catalyzed by stannous octanoate (Sn(Oct)~2~). With a microwave power level of 400, 500, 600, 700 an