✦ LIBER ✦

A critical consideration on the lack of inverted region in the Rehm—Weller plot for electron-transfer fluorescence quenching

✍ Scribed by Koichi Kikuchi; Yasutake Takahashi; Tomoharu Katagiri; Taeko Niwa; Masato Hoshi; Tsutomu Miyashi

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 494 KB
Volume: 180
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)85140-r

No coin nor oath required. For personal study only.

✦ Synopsis

The fluorescence quenching mechanism of electron donor and acceptor system in acetonitrile is discussed by taking into account the energy gap dependence of rate of outer-sphere electron-transfer reaction, the exciplex formation, and the effect of distance of interacting fluorescer and quencher.