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A critical analysis of the experimental evidence for and against a formate mechanism for high activity water-gas shift catalysts

✍ Scribed by Robbie Burch; Alexandre Goguet; Frédéric C. Meunier

Book ID
113459356
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
769 KB
Volume
409-410
Category
Article
ISSN
0926-860X

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✍ G.L. Elizarova; L.G. Matvienko; V.L. Kuznetsov; D.I. Kochubey; V.N. Parmon 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 771 KB

Catalytic activity of a large set of Fe( III)-hydroxocompounds with various well-defined structures was studied in reaction of the oxidation of water to dioxygen by Ru( bpy)i+ as an one-electron oxidizer. Fe( III)-hydroxocompounds which have the smallest distance between Fe( III) cations and a large