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A Cp2TiCl2-Me3Al (1 : 4) reagent system: An efficient reagent for generation of allylic titanocene derivatives from vinyl halides, vinyl ethers and carboxylic esters

✍ Scribed by Yuji Hanzawa; Noboru Kowase; Shu-ichi Momose; Takeo Taguchi

Book ID
108379079
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
711 KB
Volume
54
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES

Generation of allylic titanocene derivat
Generation of allylic titanocene derivatives from vinyl halides and a Cp2TiCl2ξ—ΈMe3Al reagent system
✍ Yuji Hanzawa; Noboru Kowase; Takeo Taguchi πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 241 KB

The reagent prepared in advance by stirring a mixture of a Cp2TiCI2-Me3AI reagent system in the ratio of 1 : 4 in toluene for 3 days is found to be effective in generating allylic titanocene on treatment with vinyl halides in THF.