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A Copper(II) Triflate-Catalyzed Tandem Friedel–Crafts Alkylation/Cyclization Process towards Dihydroindenes

✍ Scribed by Yugen Zhang; Liwei Chen; Ting Lu

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 163 KB
Volume: 353
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000966

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✦ Synopsis

Abstract

A one‐pot synthesis of dihydroindenes from substituted benzenes and haloalkenes was developed. The reaction proceeded via a copper(II) triflate [Cu(OTf)~2~]‐catalyzed tandem Friedel–Crafts alkylation/cyclization process with high efficiency under relatively mild conditions.

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## Abstract For Abstract see ChemInform Abstract in Full Text.