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A copper-based ionic liquid as inexpensive and efficient catalyst for the [3+2] cycloaddition of azides and terminal alkynes

✍ Scribed by Mohan, Balaji; Kang, Hyuntae; Park, Kang Hyun

Book ID
120540296
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
475 KB
Volume
35
Category
Article
ISSN
1387-7003

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Complexes of general formula [(NHC)Cu(ΞΌ-I) 2 Cu(NHC)] (NHC = 1-benzyl-3-butylbenzimidazolin-2-ylidene for 7; NHC = 1-benzyl-3-isopropylbenzimidazolin-2-ylidene for 8 NHC = 1-butyl-3-isopropylbenzimidazolin-2-ylidene for 9) and [(aNHC)CuI] {aNHC = 1-benzyl-3-methyl-4-phenyl-1H-1,2,3-triazol-3-ium-5-y