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A convenient synthetic route to mannose 6-phosphonate—cholesteryl conjugate

✍ Scribed by Sébastien Vidal; Alain Morère; Jean-Louis Montero

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 107 KB
Volume: 14
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.10134

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✦ Synopsis

Abstract

A multistep synthesis of a mannose 6‐phosphonate‐based glycolipid is described involving (1) a one‐carbon chain elongation at the 6‐position of mannose, followed by (2) phosphonation, using tris(trimethylsilyl)phosphite. This method was shown to e efficient and provides a general route to various mannose 6‐phosphonate‐based compounds for the design of drug delivery systems. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:241–246, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10134

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